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Apr 10, 20120183;32;Lowcost, highyield production of graphene nanosheets (GNs) is essential for practical applications. We have achieved high yield of edgeselectively carboxylated graphite (ECG) by a simple ball milling of pristine graphite in the presence of dry ice.
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Wet ball milling was used to exfoliate graphite platelets into graphenes in a liquid medium. Multilayered graphite nanosheets with a thickness of 30 to 80 nm were dispersed into N,Ndimethylformamide (DMF) and exfoliated by shearforcedominated ball milling carried out in a planetary mill
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The mechanism of physical reaction of ball milling process presumably contains two parts bigsized mill balls mainly exfoliated layered graphite and smallsized mill balls mostly smashed the exfoliated graphene sheets, resulting in smaller GNs and more exposed edges.
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